[2-Oxido-1-naphthaldehyde (2-hydroxybenzoyl)hydrazonato]diphenyltin(IV)
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چکیده
منابع مشابه
[2-Oxido-1-naphthaldehyde (2-hydroxybenzoyl)hydrazonato]diphenyltin(IV)
In the title compound, [Sn(C(6)H(5))(2)(C(18)H(12)N(2)O(3))], the Sn(IV) atom has a distorted trigonal-bipyramidal geometry. The Schiff base mol-ecule is coordinated to the Sn(IV) atom in a tridentate fashion via the azomethine N atom, the hydr-oxy O atom and the carbonyl O atom. The complex involves an intra-molecular O-H⋯N hydrogen bond.
متن کامل2-Benzyloxy-1-naphthaldehyde
In the title compound, C(18)H(14)O(2), the dihedral angle between the phenyl and naphthyl ring systems is 21.8 (3)°. The packing of mol-ecules in the crystal structure is stabilized by weak inter-molecular C-H⋯O hydrogen bonds.
متن کامل2-hydroxy-1-naphthaldehyde 2-methylthiosemicarbazone.
Ligands of the aroylhydrazone class have shown much promise as potential chelators for treatment of iron overload disease and perhaps cancer (Johnson et al., 1982; Baker et al., 1992; Richardson et al., 1995; Richardson & Milnes, 1997). Our previous investigations have demonstrated that 2-hydroxy-1naphthaldehyde isonicotinoyl hydrazone, (II), and several other aroylhydrazone chelators possess a...
متن کامل(2-Oxido-1-naphthaldehyde benzoylhydrazonato-κ3 N,N′,O)pyridinecopper(II)
In the mononuclear title compound, [Cu(II)(C(18)H(12)N(2)O(2))(C(5)H(5)N)], the Cu(II) ion is coordinated by two O atoms and one N atom from the dianionic tridentate L(2-) ligand (H(2)L is 2-hy-droxy-1-naphthaldehyde benzoyl-hydrazide) and one N atom from a pyridine mol-ecule in a CuN(2)O(2) distorted square-planar coordination environment.
متن کاملTautomerism in Schiff bases. The cases of 2-hydroxy-1-naphthaldehyde and 1-hydroxy-2-naphthaldehyde investigated in solution and the solid state.
Schiff bases derived from hydroxyl naphthaldehydes and o-substituted anilines have been prepared and their tautomerism assessed by spectroscopic, crystallographic, and computational methods. Tautomeric equilibria have also been studied and reveal in most cases a slight preference of imine tautomers in solution; a fact supported by DFT calculations in the gas phase as well as incorporating solve...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2009
ISSN: 1600-5368
DOI: 10.1107/s1600536809043591